There may be a time limit but I doubt it. If it's a genuine payment you should have made and missed I'd assume they are in a good position to chase it up after 4 years.
If you should have made the payment and can do so now, I'd recommend you pay it off ASAP, there's no point in delaying this and risking it blemishing your credit history (which may have longer term implications) for £195.
Jay