As long as you are simply using the car as a mode of transport then there is no need to arrange anything special with your travel insurers. You will have cover on travel insurance policies for medical treatment received as a result of an accident.
Some policies may exclude driving a vehicle under the Personal Accident section but this will be rare and only relates to a compensation payment if an accident results in the death of an insured person, loss of limb/sight or permanent total disablement. If such an exclusion is on the policy this would not affect the cover for any actual medical treatment.
Hope this helps, good luck.