Hi -- It's a good idea and one which I would use in preference, provided there are no penalty charges then overpaying your mortgage, by reducing it quicker will also reduce the overall interest payable on your mortgage at a greater rate compared to the interest earned in a poor performing ISA.
Paying off borrowed money which is usually charged at a higher rate of interest is more efficient than saving at a lower rate. The only wise thing you need to maintain is a healthy reserve of funds in case of emergency that you can easily access should the need arise.