As welshez8903 suggest, it may mean you end up paying interest in the £4. It shouldn't effect your 0% deal on the BT. Even if you're on 35% APR for purchases (the highest rate I've heard of from MBNA), because it's only £4, it would only work out at about 10p a month or so!
NatWest made an offer to me for purchases. I had to register by phone - which I did. Well, I got the 0% deal - but it seems to have start from the following day. I spent a few quid the evening I registered. So I now get an interest bill of about 21p a month in respect of the first day's purchases - repayments are being credited against the 0% purchases first.