From a legal point of view, what is on the ticket is considered an "invitation to treat". It's no more than asking you to make an offer. If the tickets get switched around and you offered the displayed price of £5 for a £20 item, then the shop is not obliged to accept your offer. Some shops will do more than others to maintain good will but, unless there was a deliberate ploy to, for example, falsely advertise "everything in the store half displayed price" then you should settle for being offered the option to return, in my view. I cannot see trading standards getting involved over one item that was probably just given the wrong ticket in error. If you wish to contact them, there will be an office near you though.