Firstly, you need to write, by recorded delivery, to the bank - explaining all you have said above.
With regard to the debt collection agency - it is in the Consumer Credit Act that the LENDER must contact you if they transfer the debt to someone else, it isn't sufficient for the agency to tell you that - it isn't relevant right now but would go against the lender if it ever gets to court. By way of explanation for the above - I could write to you saying that you must send me a check to clear your overdraft - if I used stern words and printed it in red, would you send me a cheque?
Write to the 3 major credit reference agencies (expiran etc) telling them that you have separated from him, giving both addresses. They will be able to either separate the 2 of you, or at least put a note to that effect on your record that future potential lenders will see.