On the day that you move in to new premises, you should take meter readings and pass these on to the supplier. If you didn't, all you can do is take a reading today and again tomorrow and see how that usage compares to the bill. Without meter readings, you will have to find some sensible way that both you and the supplier are happy with to canculate the usage.
If you are expecting problemswith the supplier, you can correspond in writing and keep copies and posting receipts (ask at the post office). You should mention the dates that you have been in contact in your letters.
ConsumerDirect and/or ConsumerFocus may help.