You are not always billed to an excact quarter the number fo days you are being billed over varies, this is usually decided upon when meter readings are being recieved by your supplier. There is usually a window around the date your bill is due to be released. If readings are received inside this window your quarterly bill is released based on them, if the window closes without receipt of these readings an estimated bill is sent.
To work out your primary unit allocation per bill, or billing segment. divide the total number of primary units per year by 365 and then multiply by the number of days being billed for : -
for example
(900/365)*91 = 225 (rounded)
In this example energy upto the 225th unit would be charged at one rate, everything else at the lower.
LooneyTooner is quite right in saing that the amounts you are paying, (and should be paying is quite low). From the infoamtion you have given, it seems that your actually using around £36.00 per month on your energy which would lead to an annual bill of around £432.00.
All that has happened over the year is that while you have been paying £30.00 per month your average monthly usage has actually equalled £36.00. During the summer you probably would not have noticed this as at this time your usage is generally quite low, however when you go through winter and your usage increases this shortfall becomes very apparent. If i were you and if it were possible, i'd clear the shortfall in a single payment and ask my supplier to review my MDD so that you are at a 0 balance this time next year, this will mean an increase in your MDD now, however it will save a lot of problems a year from now.
Oh and if you haven't got yourself a capped/fixed price tarriff - get one!
The answers I give you may not want to hear. The answers I give may not be easy. The answers I give will be the truth. If your prepared for this - ask away!